The synthesis of new 1,3-oxazolidines and 1,3-oxazinanes containing (η 6 -arene)tricarbonylchromium group based on condensation between aldehydes and amino alcohols

A. N. Artemov, E. V. Sazonova, N. A. Krylova, E. A. Zvereva, N. A. Pechen,G. K. Fukin,A. V. Cherkasov,V. I. Faerman,N. Yu. Grishina

Russian Chemical Bulletin(2018)

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摘要
The condensation reactions of β- and γ-amino alcohols containing phenyl or (η 6 -arene) tricarbonylchromium substituent with formaldehyde, acetaldehyde, benzaldehyde, and (η 6 -benzaldehyde)tricarbonylchromium were studied. The resulting 1,3-oxazolidine and 1,3-oxazinane products were isolated in a pure form and identified by different physicochemical methods. The effect of (η 6 -arene)tricarbonylchromium moiety on the reaction process was demonstrated.
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关键词
(η6-arene)tricarbonylchromium complexes, heterocyclic compounds, 1,3-oxazolidines, 1,3-oxazinanes, amino alcohols, aldehydes, condensation
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