Synthesis of cAAC stabilized biradical of "Me 2 Si" and "Me 2 SiCl" monoradical from Me 2 SiCl 2 - an important feedstock material.

Soumen Sinhababu,Subrata Kundu,Mujahuddin M Siddiqui,Alexander N Paesch,Regine Herbst-Irmer,Brigitte Schwederski,Pinaki Saha,Lili Zhao,Gernot Frenking,Wolfgang Kaim,Dietmar Stalke,Herbert W Roesky

CHEMICAL COMMUNICATIONS（2019）

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摘要

The cyclic alkyl(amino) carbene (cAAC) coordinated biradical of dimethylsilicon was isolated as (cAAC)(2)Me2Si (1), (cAAC = C(CH2)(CMe2)(2)N-2,6-i-Pr2C6H3), synthesized from the reduction of Me2SiCl2 using two equivalents of KC8 in the presence of two equivalents of cAAC. The reduction of Me2SiCl2 by one equivalent of KC8 in the presence of one equivalent of cAAC resulted in the stable dimethylsiliconchloride monoradical (cAAC)Me2SiCl (2).

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