A kinetic study, thermal analysis and kinetic modeling on homo and copolymerization of 2-(N,N-diethylamino)ethyl methacrylate and PEGMA

Priscila Quiñonez-Angulo,Jesús Ruiz-Villegas,Angel Licea-Claverie,Alejandro Ramirez-Jiménez,Valentín Miranda-Soto,Iván Zapata-González

European Polymer Journal（2018）

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摘要

•Estimation of the values of kp/kt1/2 for the involved monomers.•Estimation of reactivity ratios and nonideal random sequence of the copolymers.•Modulation of the Tg values in the range −61 ≤ Tg ≤ 20 °C, depending on the copolymer composition.•Comparison of the experimental data and a basic kinetic model.

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关键词

Smart copolymers,Reactivity ratios,Kinetic parameters,DEAEMA/PEGMA,Thermal analysis,Kinetic modeling

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