Asymmetric synthetic approach to a functionalized azabicyclo[3.3.1]nonane moiety of (+)-sarain A

Tetrahedron Letters（2017）

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摘要

•Asymmetric approach to a functionalized bicyclic core of sarain A.•Highly selective asymmetric Diels-Alder cycloaddition.•A facile aza-Michael addition to form the azabicyclo[3.3.1]nonane motif.

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关键词

Sarain A,Natural product,Diels-Alder cycloaddition,Aza-Michael addition,Asymmetric synthesis

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