A modular synthesis approach to multinuclear heterometallic oxo clusters in polyoxometalates.

Takuo Minato,Kosuke Suzuki,Yusuke Ohata,Kazuya Yamaguchi,Noritaka Mizuno

CHEMICAL COMMUNICATIONS（2017）

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摘要

We report a "modular synthesis approach" to multinuclear heterometallic oxo clusters in lacunary polyoxometalates (POMs). This approach allowed the synthesis of a POM containing a nonanuclear {CrMn4}Lu2Ag2 cluster with the widest variety of metals among the discrete metal oxo clusters prepared to date.

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