Synthesis and solubility measurement in supercritical carbon dioxide of two solid derivatives of 2-methylnaphthalene-1,4-dione (menadione): 2-(Benzylamino)-3-methylnaphthalene-1,4-dione and 3-(phenethylamino)-2-methylnaphthalene-1,4-dione

The Journal of Chemical Thermodynamics(2016)

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摘要
•Two menadione derivatives were synthesized, purified and characterized.•Solubility of menadione derivatives in SC-CO2 was measured at T<333K, p<28MPa.•Thermodynamic consistency of solubility data measured was evaluated.•Solubility data was correlated in terms of temperature and CO2 density.
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关键词
Solubility,Menadione,Derivatives,Supercritical carbon dioxide,Modelling
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