Synthesis of a new photoresponsive molecular carcerand

Satya Narayan Sahu,Alexander B. Rozhenko,Jens Eberhard,Jochen Mattay

Journal of Photochemistry and Photobiology A: Chemistry（2016）

引用 7|浏览12

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摘要

•A new photoresponsive molecular capsule with a “switchable wall” is synthesized.•UV/vis-irradiation induces eversible trans to cis isomerisation.•Quantum chemical calculations indicate increasing flexibility starting from all-trans to all-cis.

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关键词

Azobenzene,Resorcin[4]arene cavitand,Carcerand,Molecular capsule,Cis–trans isomerization,DFT

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