Electrochemical epoxidation of olefins
CATALYSIS TODAY(1988)
摘要
Propene and the four isomeric butenes are selectively oxidized to the respective epoxides by reaction with electrachemically generated silver(II)-pyridine ions. From kinetic studies, the epoxidation was derived to involve the transfer of an electrophilic oxygen atom from a transient silver(III)-oxide complex to the homogeneously dissolved olefin.
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关键词
reaction kinetics,catalytic activity,chemical reaction,complex data,analytical chemistry,exploratory study,kinetics
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