New disiloxane based on N -acetylvaline: synthesis and structure

A. A. Nikolin,A. A. Korlyukov, E. P. Kramarova,D. E. Arkhipov,A. G. Shipov,Yu. I. Baukov,Vad. V. Negrebetsky

RUSSIAN CHEMICAL BULLETIN（2018）

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摘要

Silylmethylation of N -acetylvaline with the ClCH 2 SiMe 2 Cl—(Me 3 Si) 2 NH system gave the previously unknown 2-silamorpholin-6-one derivative, whose hydrolysis in aqueous ethanol produced bis-acetylvaline-containing disiloxane. The X-ray diffraction study and quantum chemical calculations demonstrated that both silicon atoms in the final product are four-coordinated.

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关键词

silicon-containing amino acids,disiloxanes,synthesis,X-ray diffraction,quantum chemical calculations

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