Formation and C-F Bond Functionalization of [P,N]-Ligated Perfluoronickelacyclopentanes

Kaitie A. Giffin,Lorraine A. Pua,Ilia Korobkov,R. Tom Baker

Polyhedron（2019）

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摘要

Synthesis and characterization of [P,N]-ligated perfluoronickelacyclopentanes based on the bidentate ligand 2-(diphenylphosphino)phenyl-N-phenylaniline [P,NH] are reported. Reactivity studies of the phosphinoamine [P,NH]- and anionic phosphinoamide [P,N−]-ligated perfluoronickelacycles are presented.

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关键词

Metal organofluorine chemistry,Bifunctional ligands,C–F bond activation,Organonickel chemistry

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