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We have investigated the effect of co-doping of nitrogen (N) acceptor impurity on the structural and magnetic properties of (Zn,Fe)Te. We grew (Zn,Fe)Te:N thin films by molecular beam epitaxy (MBE) with a fixed Fe composition 1.5% and varied N concentrations in the range of [N] = 8 × 1017– 4 × 1019 cm−3. Structural analyses by using x-ray absorption fine structure (XAFS) and transmission electron microscope (TEM) reveal that N-doped films with intermediate N concentration [N] = 8 × 1017– 7 × 1018 cm−3 are mainly composed of pure diluted phase with substitutional Fe atoms in the valence state deviated from Fe2+, while Fe is dominantly incorporated in an Fe-N compound at the highest N concentration [N] = 4 × 1019 cm−3. Accordingly, the magnetization measurement using SQUID confirms a drastic change of magnetic properties; a linear dependence of magnetization of magnetic field (M-H), typical of van-Vleck paramagnetism in the film without N-doping changes into ferromagnetic behaviors with a hysteretic M-H curves at the intermediate N concentrations and comes back to a linear M-H dependence at the highest N concentration. The ferromagnetism in the intermediate [N] range may reflect a deviation of the valence state of the substitutional Fe from Fe2+, while the linear M-H at the highest [N] would be attributed to precipitates of an Fe-N compound.