Catalytic fast pyrolysis with metal-modified ZSM-5 catalysts in inert and hydrogen atmospheres
Journal of Analytical and Applied Pyrolysis(2018)
摘要
•ZSM-5 was modified by Ga, Ni, Cu, Co, or Pt incorporation.•Hydrocarbon and coke yields were proportional to number of strong acid sites in inert.•With added hydrogen, metals reduced coke formation by hydrogen activation.•Ni/ZSM-5 produced vapors with high ratio of hydrocarbons to oxygenates.
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关键词
Catalytic pyrolysis,ZSM-5,Metal,Hydrogen,Deactivation,Pine
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