Practical, high-yield synthesis of thiol-terminated diacetylenes for formation of conductive monolayers

Tetrahedron Letters(2018)

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摘要
•The synthesis of thiol-terminated diacetylenes reported herein proceeds in 75–80% overall yields.•Used sequential ‘acetylene zipper’ reaction, a Sonagashira coupling procedure for diactylene formation.•Thioacetate product allows long term storage without resorting to using the disulfides.
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关键词
Conjugated diacetylene,Self-assembled monolayer,Conductive monolayer,Photonics
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