First protection-free protocol for synthesis of 1-deoxy sugars through glycosyl dithiocarbamate intermediates

Gefei Li,Masato Noguchi, Kensuke Nakamura, Ryohei Hayasaka,Yuuki Tanaka,Shin-ichiro Shoda

Tetrahedron Letters（2018）

引用 3|浏览25

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摘要

•Unprotected glycosyl dithiocarbamates as a useful intermediate for 1-deoxy sugar synthesis.•No protecting-groups are needed to prepare 1-deoxy sugars.•The 1-deoxy sugars help to elucidate the role of carbohydrates in metabolic cycles.

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关键词

1-Deoxy sugar,Glycosyl dithiocarbamate,Protection-free synthesis,Direct anomeric activation,Radical desulfurization

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