Transition metal catalyzed asymmetric cyclopropanation via diazo decomposition: Ligand architecture defining stereoselectivity
SYNTHETIC COMMUNICATIONS(2018)
摘要
Asymmetric cyclopropanation of alkenes through diazo decomposition mediated by transition metal complexes is a widely investigated catalytic reaction to obtain cyclopropanes where high enantioselectivity is achieved by optimizing metal-ligand combination. Instead of a chronological listing of developments, this review illustrates the existing literature data according to the structural types of ligands in catalytic complexes and attempts to correlate substrate structure and selectivity with ligand design. [GRAPHICS] .
更多查看译文
关键词
Asymmetric cyclopropanation,chiral ligand,diazo decomposition,ligand symmetry
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要