Poly(Styrene-Divinyl Benzene)-Immobilized Fe(Iii) Complex Of 1,3-Bis(Benzimidazolyl)Benzene: Efficient Catalyst For The Photocatalytic Degradation Of Xylenol Orange

A polymer-supported Fe(III) complex of 1,3-bis(benzimidazolyl)benzene [PS-Fe(III)BBZNH] was used in the photodegradation of xylenol orange (XO) dye with H2O2 under UV irradiation. The catalyst was synthesized and characterized by elemental analysis, and Fourier transform infrared, far-infrared, and UV-visible-diffuse reflectance spectroscopy, Scanning electron microscopy, Brunauer-Emmett-Teller surface area measurements, thermogravimetric analysis, and magnetic measurements. An octahedral coordination around Fe(III) was confirmed by electronic spectral data, and a decrease in the intensity of the (CH2Cl) peak in PS-Fe(III)BBZNH was observed compared to the polymer support; this indicated the binding of the ligand to the support. An array of experiments were carried out to assess the influence of various reaction parameters on its photocatalytic performance to ensure maximum dye degradation. The maximum photocatalytic activity was observed at pH8 with 125mg of catalyst, 300ppm of XO, and 200ppm of H2O2 with complete mineralization after 90min, as confirmed by chemical oxygen demand measurements. Furthermore, the reactions were repeated under sunlight and under dark conditions to check the photocatalytic efficiency of PS-Fe(III)BBZNH. It displayed better catalytic performance compared than the unsupported complex, PS-Cu(II)BBZNH [Cu(II) complex of 1,3-bis(benzimidazolyl)benzene], and PS-VO(IV)BBZNH [VO(IV) complex of 1,3-bis(benzimidazolyl)benzene]. PS-Fe(III)BBZNH could be recycled for up to seven runs. A tentative mechanism involving OH radical was proposed. (c) 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46480.