Duplex component additive of tris(trimethylsilyl) phosphite-vinylene carbonate for lithium sulfur batteries
Energy Storage Materials(2018)
摘要
The practical application of lithium–sulfur battery, one of the most promising batteries close to market, is hindered by its poor cyclibility. Herein, Tris(trimethylsilyl) phosphite-Vinylene carbonate (TMSP-VC) is firstly investigated as a duplex-component additives to prolong the cycle life and enhance the rate performance of Li-S batteries. TMSP and VC function synergistically to modify the interfacial film of sulfur cathode and Li anode, and accelerate the lithium ion diffusion. Using traditional carbonate electrolyte with 1 wt%TMSP-2 wt%VC additives, S@pPAN cathode delivers a reversible capacity of 1243 mA h g−1 over 800 cycles at 1 C, and a discharge capacity of 990 mA h g−1 at the extremely high rate of 20 C.
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关键词
Li-S batteries,TMSP-VC,Electrolyte additives,Electrochemical performance
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