Preparation of Composite Films of Methacryloyl-modified Lignocresol and Polylactic Acid

BIORESOURCES(2018)

引用 1|浏览5
暂无评分
摘要
Methacryloyl chloride was grafted onto lignocresol to increase the acyl content of lignocresol and to enhance the interfacial compatibility of lignocresol and polylactic acid. The physical and mechanical properties of the modified lignocresol sample were studied. The methacryloyl-modified lignocresol was characterized by infrared spectroscopy (IR), ultravioletvisible (UV) spectroscopy, and gel permeation chromatography (GPC). Unmodified and modified lignocresol samples were used to prepare composite films with polylactic acid, and its tensile strengths and elongations at breaks were analyzed after film formation. Thermal stabilities were evaluated by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The results indicated that methacryloyl group was successfully grafted onto lignocresol, and that the optimum dosage of methacryloyl chloride required was 0.5 mL per 0.5 g of lignocresol. When unmodified lignocresol was added to polylactic acid, the tensile strength gradually decreased as the amount of lignocresol increased. However, the composite films prepared from the methacryloylmodified lignocresol exhibited a slower decline in tensile strength and displayed an increased elongation at break. The optimum mechanical properties were found using a 10% blend of modified lignocresol with polylactic acid.
更多
查看译文
关键词
Lignocresol,Methacryloyl chloride,Polylactic acid (PLA),Blend composite films
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要