Distribution, cycling and impact of water in the Earth's interior

The Earth's deep interior is a hidden water reservoir on a par with the hydrosphere that is crucial for keeping the Earth as a habitable planet. In particular, nominally anhydrous minerals (NAMs) in the silicate Earth host a significant amount of water by accommodating H point defects in their crystal lattices. Water distribution in the silicate Earth is highly heterogeneous, and the mantle transition zone may contain more water than the upper and lower mantles. Plate subduction transports surface water to various depths, with a series of hydrous minerals and NAMs serving as water carriers. Dehydration of the subducting slab produces liquid phases such as aqueous solutions and hydrous melts as a metasomatic agent of the mantle. Partial melting of the metasomatic mantle domains sparks off arc volcanism, which, along with the volcanism at mid-ocean ridges and hotspots, returns water to the surface and completes the deep water cycle. There appears to have been a steady balance between hydration and dehydration of the mantle at least since the Phanerozoic. Earth's water probably originates from a primordial portion that survived the Moon-forming giant impact, with later delivery by asteroids and comets. Water could play a critical role in initiating plate tectonics. In the modern Earth, the storage and cycling of water profoundly modulates a variety of properties and processes of the Earth's interior, with impacts on surface environments. Notable examples include the hydrolytic weakening effect on mantle convection and plate motion, influences on phase transitions (on the solidus of mantle peridotite in particular) and dehydration embrittlement triggering intermediate-to deep-focus earthquakes. Water can reduce seismic velocity and enhance electrical conductivity, providing remote sensing methods for water distribution in the Earth's interior. Many unresolved issues around the deep water cycle require an integrated approach and concerted efforts from multiple disciplines.