Organocatalyzed oxidation of benzyl alcohols by a tetrazole-amino-saccharin: A combined experimental and theoretical (DFT) study

Luís M.T. Frija,Maxim L. Kuznetsov,Bruno G. M. Rocha,Lília I. L. Cabral,M. Lurdes S. Cristiano,Maximilian N. Kopylovich,Armando J. L. Pombeiro

Molecular Catalysis（2017）

引用 17|浏览11

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摘要

•Oxidation of benzyl alcohols mediated by a tetrazole-amino-saccharin organocatalyst.•DFT calculations indicate alcohol oxidation via a free radical mechanism.•Solvent-free and microwave assisted process using TBHP as oxidant.

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关键词

Organocatalysis,Tetrazole,Saccharin,Benzyl alcohol oxidation,DFT calculations

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