Magnetic properties of rare-earth sulfide YbAgS2
Physica B: Condensed Matter(2018)
摘要
We have succeeded in synthesizing single-phase polycrystalline samples of YbAgS2 belonging to the tetragonal system with space group I41md. YbAgS2 shows an antiferromagnetic transition at TN=6.6K. The effective magnetic moment is in good agreement with the theoretical value for Yb3+ free ion. A broad anomaly is observed just above TN in the temperature dependence of magnetic susceptibility. The entropy released at TN is only about half of Rln2 expected for a Kramers doublet ground state. We consider that these phenomena are due to the existence of short-range magnetic correlations rather than the partial screening of the Yb moments by conduction electrons via the Kondo effect.
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关键词
Ytterbium silver sulfide,Magnetization,Specific heat,Zintl phases
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