Fist oxidovanadium complexes containing chiral derivatives of dihydrophenanthroline and diazafluorene

Yakov S. Fomenko,Artem L. Gushchin,Aleksey V. Tkachev,Evgene S. Vasilyev,Pavel A. Abramov,Vladimir A. Nadolinny,Mikhail M. Syrokvashin,Maxim N. Sokolov

Polyhedron（2017）

引用 13|浏览1

暂无评分

摘要

Reactions of VCl3 with chiral derivatives of dihydrophenanthroline (L1) and diazafluorene (L2) result in oxo complexes of V(III) and V(IV) which are further transformed to V(V) complexes in coordinating solvents. The [VVO(L1)(OMe)Cl2] complex was isolated from methanol and characterized by XRD analysis and represent the first oxovanadium complex with chiral diimine ligand.

查看译文

关键词

Chiral ligands,Oxido complexes,Vanadium,Crystal structure,EPR

AI 理解论文

溯源树

样例

生成溯源树，研究论文发展脉络

Chat Paper

正在生成论文摘要