Electron-rich phenanthroline as organic linkers in molybdenum oxide layered hybrid

Shen V. Chong,Islah-u-din,Jeffery L. Tallon

Materials Letters（2017）

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摘要

•New organic-inorganic layered hybrids containing electron-rich 3,8-phenanthroline organic linkers.•Electron-doping produces reduced molybdenum species which cause an upturn in magnetization at low-temperature.•A non-zero electronic specific heat coefficient that is higher than its bipyridyl counterpart.•The electronic density-of-states is further increased via hydrogen intercalation.

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关键词

Organic-inorganic hybrids,Polycyclic aromatic hydrocarbons,Molybdenum oxide,Pauli paramagnetism,Specific heat capacity

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