Reaction of formaldehyde over birnessite catalyst: A combined XPS and ToF-SIMS study

S. Selvakumar,Nicolas Nuns,Martine Trentesaux,V.S. Batra,Jean-Marc Giraudon,Jean-François Lamonier

Applied Catalysis B: Environmental（2018）

引用 54|浏览26

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摘要

•Birnessite surface area much higher than those reported in the literature.•Redox mechanism evidenced by combined XPS and ToF-SIMS analyses.•Molecular information of birnessite and intermediates products interface.•Different intermediates formation and their conversion at Mn and K sites.

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关键词

Formaldehyde,Birnessite,Catalytic oxidation,X-Ray photoelectron spectroscopy,Time of flight secondary ion mass spectrometry

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