A real support effect on the hydrodeoxygenation of methyl oleate by sulfided NiMo catalysts

Catalysis Today（2017）

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摘要

•Support effect on sulfided NiMo in methyl oleate hydrodeoxygenation investigated.•Lewis acidity due to Al3+ catalyses methyl ester hydrolysis.•Deactivation when using Lewis acidic (alumina, silica-alumina) supports.•Silica and activated carbon based catalysts display stable HDO performance.•Activated carbon highest catalytic performance for HDO methyl oleate to green diesel.

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关键词

Hydrodeoxygenation,Support effect,NiMo sulfide,Methyl oleate,Deactivation

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