Coordination behaviour of 1-(3,2':6',3''-terpyridin-4'-yl)ferrocene: structure and magnetic and electrochemical properties of a tetracopper dimetallomacrocycle
Polyhedron(2017)
摘要
The divergent ligand 1-(3,2′:6′,3″-terpyridin-4′-yl)ferrocene reacts with CuCl2 to assemble a tetracopper dimetallomacrocycle supported by a pair of μ-Cl ligands; the copper(II) dimer exhibits a weak antiferromagnetic coupling via the bridging chlorido ligands.
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关键词
Copper,Divergent terypyridine,Ferrocene,Structure,Magnetism,Electrochemistry
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