Synthesis of novel d-glucose based anionic bolaamphiphiles and their catalytic application in 1,3-dipolar nitrone cycloaddition reactions

Catalysis Communications, pp. 77-81, 2017.

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Keywords:
d-GlucoseBolaamphiphilesSelf-assemblyNitrone cycloadditionStereoselectivityMore(1+)

Abstract:

Three d-glucose based bolaamphiphiles have been synthesized by a simple and efficient synthetic methodology utilizing the free C-3 hydroxyl group of diisopropylidene glucose. The resulting bolaamphiphiles showed unique aggregation behavior in aqueous solution, e.g. transformation of vesicle to tubular morphology on aging. The chiral hydro...More

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