Eco-friendly sol-gel derived sodium-based ormolytes for electrochromic devices

M. Fernandes,Rita Daniela Barros Leones,Sónia Pereira,Ana M. S. Costa,João F. Mano,Maria Manuela Silva,Elvira Fortunato,V. de Zea Bermudez,R. Rego

Electrochimica Acta（2017）

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摘要

•Two series of ormolytes doped with NaCF3SO3 were prepared by the sol-gel route.•The samples are thermally stable up to ca. 250°C.•Best room temperature conductivity was attained with a poly(ε-caprolactone)/siloxane network.•An ECD with a POE/siloxane-based ormolyte produced a coloration efficiency of −116cm2C−1 at 555nm.

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关键词

organic/inorganic hybrid ormolytes,poly(ε-caprolactone)(530)/siloxane,poly(oxyethylene)/siloxane,sodium triflate,electrochromic devices

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