Effect of anions on the reaction of Mn(II) cation with a tetradentate nitrogen ligand: Syntheses, crystal structures and spectroscopic properties

Polyhedron（2017）

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摘要

Mononuclear complex [MnII(L)(Cl)(DMF)](ClO4) (1) and binuclear complex [MnII(L)(OAc)]2(ClO4)2·DMF·0.5H2O (2) were synthesized and characterized. The difference is that complex 1 was synthesized with MnCl2·4H2O, and 2 was synthesized with Mn(OAc)2·4H2O as MnII cations.

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关键词

Mn(II) ions,Tetradentate nitrogen ligand,Crystal structure,Anion affect,Synthesis

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