Correlation Effects On The Fine-Structure Splitting Within The 3d(9) Ground Configuration In Highly-Charged Co-Like Ions

CHINESE PHYSICS B(2016)

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摘要
A comprehensive theoretical study of correlation effects on the fine-structure splitting within the ground configuration 3d(9) of the Co-like Hf45+, Ta46+, W47+, and Au52+ ions is performed by employing the multi-configuration Dirac-Hartree-Fock method in the active space approximation. It shows that the core-valence correlation with the inner-core 2p electron is more significant than with the outer 3p and 3s electrons, and the correlation with the 2s electron is also noticeable. The core-core correlation seems to be small and can be ignored. The calculated D-2(3/2,5/2) splitting energies agree with the recent electron-beam ion-trap measurements [Phys. Rev. A 83 032517 (2011), Eur. Phys. J. D 66 286 (2012)] to within the experimental uncertainties.
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关键词
correlation effects, multi-configuration Dirac-Hartree-Fock method, high-Z Co-like ions, fine-structure splitting
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