Synthesis and characterization of first row transition metal p-toluenesulfonate complexes and chains

Philp J. Ferko,Jeffrey R. Withers, Hung Nguyen,Charles Allison,Joshua Ema,Tim Ema,Nigam P. Rath,Yuan-Zhu Zhang,Stephen M. Holmes

Polyhedron（2017）

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摘要

The structures, magnetism, and spectroscopic properties of several 3d transition metal p-toluenesulfonate complexes and chains are described. A one-dimensional chain {trans-CrII(DMF)2(OTs)2}n·nH2O (1) and mononuclear complexes of {trans-[MII(OTs)2(DMF)4]}·nH2O (MII=Fe, 2; Co, 3; n=1, 0) and [NiII(DMF)4][OTs]2 (4) stoichiometry are described.

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关键词

Crystal structures,Magnetic properties,Polynuclear complexes

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