Synthesis of Alkoxymethyl Groups Containing Isoxazoles and Chromones

SYNTHESIS-STUTTGART(2017)

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摘要
An oxocarbenium ion mediated cyclization of (Z)-1,3-diaryl-prop-2-yn-1-one O-methyloximes and 3-arylprop-2-yn-1-(2-methoxyphenyl)-1-ones resulted in regioselective formation of functionalized isoxazoles and chromones, respectively. Alkoxy(aryl) methyl group containing compounds were obtained in good and high yields.
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关键词
isoxazoles,chromones,electrophile-mediated cyclization,oxocarbenium ion
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