Bildung von Iodoantimonaten und -bismutaten. Kristallustrukturen von (PhCH2NEt3)4[Sb6I22], (PhCH2NEt3)4[Bi6I22] und (Ph4P)3[Bi5I18]
Zeitschrift für Naturforschung. B, A journal of chemical sciences（1994）
摘要
The formation and the crystal structures of the title compounds are reported, (PhCH 2 NEt 3 ) 4 [Sb 6 I 22 ] and (PhCH 2 NEt 3 ) 4 [Bi 6 I 22 ] are isotypic and contain a novel [E 6 I 22 ] 4- anion (E=Sb, Bi). The anion of (Ph 4 P 3 [Bi 5 I 18 ] consists of a linear chain of five face-sharing [BiI 6 ] octahedra
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