Enhancement of Electron Transfer in Various Photo-Assisted Oxidation Processes for Nitro-Phenolic Compound Conversion

Journal of Electronic Materials(2016)

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摘要
The present study focuses on photo-assisted advanced oxidation processes (AOPs) with strongly enhanced electron transfer for degradation of nitro-phenolic compounds in aqueous medium. The effectiveness of these processes was estimated based on the pseudo-first order rate constant k determined from high-performance liquid chromatography. The degradation of four different nitro-phenolic compounds was systematically studied using selected AOPs; these four compounds were nitrophenol, dinitrophenol, trinitrophenol and trinitroresorcin. It was observed that the combination of ultraviolet light with hydrogen peroxide H 2 O 2 enhanced and maintained hydroxyl radicals, and therefore increased the conversion yield of organic pollutants. These AOPs provided efficient and green removal of stable organic toxins found in a wide range of industrial wastewater.
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关键词
Electrooxidation,photo-assisted,electronic transfer processes,nitrophenols
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