Merging host-guest chemistry and organocatalysis for the chemical valorization of CO2

Catalysis Today(2017)

引用 13|浏览17
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摘要
•Host-guest systems greatly affect CO2 incorporation into cyclic carbonates.•Phosphonate cavitands are suitable hosts for ammonium recognition.•Activity is correlated to the binding strength in the ammonium/cavitand association.•Cooperative effect of acidic hydroxyls and binding properties of cavitand hosts.
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关键词
CO2 valorization,Cyclic carbonates,Host-guest chemistry,Organocatalysis,Supramolecular chemistry,Cavitands
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