Enantioselective Construction of Quaternary Carbon Stereocenter via Palladium-Catalyzed Asymmetric Allylic Alkylation of Lactones

Xiao-Hui Li,Shi-Li Wan,Di Chen,Qing-Rong Liu,Chang-Hua Ding,Ping Fang,Xue-Long Hou

SYNTHESIS-STUTTGART（2016）

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摘要

An efficient and practical method for the synthesis of ,-disubstituted six-membered lactones was developed. Enantioselective construction of quaternary carbon centers by utilizing Pd-catalyzed asymmetric allylic alkylation proved its feasibility.

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关键词

palladium,allylic alkylation,asymmetric catalysis,lactones,quaternarycarbon

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