Synthesis and magnetic properties of a dinuclear manganese(II) complex with two manganese(II) ions of C2-twisted octahedral geometry

Hiroshi Sakiyama, Masatoshi Kato, Satoshi Sasaki,Moriya Tasaki,Eiji Asato,Masayuki Koikawa

Polyhedron（2016）

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摘要

A dinuclar manganese(II) complex [Mn2(sym-hcp)2](BPh4)2·2acetone·2H2O (1) has a bis(μ-phenoxo)dimanganese(II) core structure. Magnetic data indicates weak antiferromagnetic interaction (2J=−0.93cm−1) between the manganese(II) ions.

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关键词

Dinuclear manganese(II) complex,Di-μ-phenolato bridge,Dinucleating ligand,Crystal structure,Magnetic properties

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