Promotion Of Self-Assembly Patterning Of Fept Nanoparticles By Tuning The Concentration Of Oleylamine/Oleic Acid Surfactants In A Coating Solution

To provide a bit-patterned perpendicular magnetic recording medium consisting of an array of FePt magnetic nanoparticles, the effect of the total dispersant concentrations of oleylamine and oleic acid in a FePt-nanoparticle/toluene coating solution on a self-assembled nanoparticle array with a long-range periodicity on a flat SiO2/Si substrate and two patterned substrates, respectively, was examined. At a surfactant concentration greater than 0.8 vol%, FePt nanoparticles with an average size of 4.4 nm were arrayed in a two-dimensional and hexagonal-close-packed ordered array with 8.3-nm pitches on the flat surface. Self-assembled nanoparticles were arrayed on the bottom surface of the patterned trench, the array exhibited a hexagonal-close-packed structure. Furthermore the line defects in the arrays are caused by the waviness of the trench walls, and the surface roughness. (C) 2016 The Electrochemical Society. All rights reserved.