Preparation of Heterocycles via Visible-Light-Driven Aerobic Selenation of Olefins with Diselenides
Organic Letters(2019)
摘要
The aerobic dehydrogenative cyclization of alkenes with easily accessible diselenides facilitated by visible light is reported. Notably, the features of this transition-metal-free protocol are pronounced efficiency and practicality, good functional group tolerance, atom economy, and high sustainability, since ambient air and visible light are adequate for the clean construction of five- and six membered heterocycles in yields of up to 98%.
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