Thermodynamics of plutonium(iii) and curium(iii) complexation with a N-donor ligand.
DALTON TRANSACTIONS(2019)
摘要
The complexation of Pu(III) and Cm(III) with a soft N-donor ligand was investigated using the van't Hoff method, microcalorimetry and DFT calculations. The studies revealed that the strength of the actinide-ligand bond as given by the enthalpic contribution drastically decreases on going from Pu(III) to Cm(III), while the complex stability remains nearly constant.
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关键词
ligand,complexation,n-donor
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