Dehydrative Allylation between Aldehydes and Allylic Alcohols through Synergistic N-Heterocyclic Carbene/Palladium Catalysis.

Hiroki Haruki,Shigeo Yasuda,Kazunori Nagao,Hirohisa Ohmiya

CHEMISTRY-A EUROPEAN JOURNAL（2019）

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摘要

Dehydrative allylation between widely available aldehydes and allylic alcohols to afford beta,gamma-unsaturated ketones was enabled by a synergistic merger of a thiazolium N-heterocyclic carbene catalyst and a palladium-bisphosphine catalyst.

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关键词

aldehyde,carbene,dehydrative allylation,palladium,synergistic catalysis

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