Probing Lewis Acid-Base Interactions In Single-Molecule Junctions

Xunshan Liu,Xiaohui Li,Sara Sangtarash,Hatef Sadeghi,Silvio Decurtins,Robert Häner,Wenjing Hong,Colin J Lambert,Shi-Xia Liu

NANOSCALE（2018）

引用 16|浏览47

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摘要

A novel strategy to regulate the tunneling mechanism for charge transport through an organoborane wire via Lewis acid-base interactions has been developed. A change from LUMO- to HOMO-dominated charge transport upon the addition of the fluoride is verified both experimentally and theoretically.

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