Amino Acid Chiral Selection Via Weak Interactions in Stellar Environments: Implications for the Origin of Life

SCIENTIFIC REPORTS(2018)

引用 15|浏览7
暂无评分
摘要
Magnetochiral phenomena may be responsible for the selection of chiral states of biomolecules in meteoric environments. For example, the Supernova Amino Acid Processing (SNAAP) Model was proposed previously as a possible mode of magnetochiral selection of amino acids by way of the weak interaction in strong magnetic fields. In earlier work, this model was shown to produce an enantiomeric excess ( ee ) as high as 0.014% for alanine. In this paper we present the results of molecular quantum chemistry calculations from which ee s are determined for the α -amino acids plus isovaline and norvaline, which were found to have positive ee s in meteorites. Calculations are performed for both isolated and aqueous states. In some cases, the aqueous state was found to produce larger ee s reaching values as high as a few percent under plausible conditions.
更多
查看译文
关键词
Astrobiology,Computational astrophysics,Chemical origin of life,Science,Humanities and Social Sciences,multidisciplinary
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要