Real-space evidence of Watson-Crick and Hoogsteen adenine-uracil base pairs on Au(111).

From the interplay of high-resolution scanning tunneling microscopy imaging and density functional theory calculations, we show the real-space evidence of the formation of Watson-Crick and Hoogsteen adenine-uracil base pairs on an Au(111) surface with the employment of base derivatives, and further investigate the relative stability of the two types of adenine-uracil base pairs.