Palladium-catalyzed intermolecular carbonylative cross-coupling of heteroaryl C(sp 2 )-H bonds with amines: an efficient strategy for oxidative aminocarbonylation of azoles.
CHEMICAL COMMUNICATIONS(2017)
摘要
An efficient palladium-catalyzed oxidative aminocarbonylation of azoles has been developed. This system allows for intermolecular carbonylative cross-coupling of aromatic C(sp(2))-H bonds with simple amines, which has often been asked for, but has not been realized so far. It provides a straightforward approach to a variety of azol-2-amides.
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