Simulated photoelectron intensities at the aqueous solution-air interface for flat and cylindrical (microjet) geometries.

Giorgia Olivieri,Krista M Parry,Cedric J Powell,Douglas J Tobias,Matthew A Brown

PHYSICAL CHEMISTRY CHEMICAL PHYSICS（2017）

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摘要

Ion spatial distributions at the aqueous-air/ vacuum interface are accessible by energy-dependent X-ray photoelectron spectroscopy (XPS). Here we quantify the difference between a flat surface and a cylindrical microjet in terms of the energy-dependent information depth of the XPS experiment and in terms of the simulated photoelectron intensities using solutions of pure water and of 1 mol L-1 NaI as examples.

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关键词

Ambient Pressure Photoelectron Spectroscopy,Photoelectrodes,X-ray Photoelectron Spectroscopy,Environmental Scanning Electron Microscopy,Scanning Electron Microscopy

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