"Molecular Nanoclusters": A 2-Nm-Sized {Mn-29} Cluster With A Spherical Structure

Dimitris I Alexandropoulos,Adeline Fournet,Luís Cunha-Silva,George Christou,Theocharis C Stamatatos

INORGANIC CHEMISTRY（2016）

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摘要

The comproportionation reaction between Mn-II and Mn-VII sources in the presence of 3,3-dimethylacrylic acid and azides has led to a new {Mn-29} molecular cluster with a spherical structure and dimensions of similar to 2.2 nm, comparable in size to the smallest classical and magnetic nanoparticles.

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