Thermal and near-infrared light induced spin crossover in a mononuclear iron(ii) complex with a tetrathiafulvalene-fused dipyridophenazine ligand.

F Pointillart,X Liu,M Kepenekian,B Le Guennic,S Golhen,V Dorcet, T Roisnel,O Cador, Z You,J Hauser,S Decurtins, L Ouahab,S-X Liu

DALTON TRANSACTIONS（2016）

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摘要

A mononuclear Fe(II) complex involving a tetrathiafulvalene-based ligand exhibits thermal spin-crossover (around 143 K) with pronounced hysteresis behaviour (48 K). The chromophoric and pi-extended ligand allows Near-Infrared (NIR) sensitization for the light-induced excited spin-state trapping (LIESST) with T(LIESST) = 90 K.

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