B(C6F5)3-Catalyzed Deoxygenation of Sulfoxides and Amine N-Oxides with Hydrosilanes

Ding Fangwei,Jiang Yanqiu,Gan Shaoyan,Bao Robert Li-Yuan,Lin Kaifeng,Shi Lei

European Journal of Organic Chemistry（2017）

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摘要

An efficient strategy for the deoxygenation of sulfoxides and amine N-oxides by using B(C6F5)(3) and hydrosilanes was developed. This method provided the corresponding aromatic and aliphatic products in good to high yields and showed good functional-group tolerance under mild conditions.

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关键词

Amines,Deoxygenation,Hydrosilanes,Lewis acids,Sulfur

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