Cyclopentanone derivatives from 5-hydroxymethylfurfural via 1-hydroxyhexane-2,5-dione as intermediate.

Bartosz Wozniak,Anke Spannenberg,Yuehui Li,Sandra Hinze,Johannes G de Vries

CHEMSUSCHEM（2018）

引用 43|浏览4

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摘要

An efficient strategy for the conversion of biomass derived 5-hydroxymethylfurfural (HMF) into 2-hydroxy-3-methylcyclopent-2-enone (MCP) by an intramolecular aldol condensation of 1-hydroxyhexane-2,5-dione (HHD) has been developed. Further transformations of MCP towards the diol, enol acetate, levulinic acid and N-heterocyclic compounds are also reported.

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关键词

biomass,cycloketones,homogeneous catalysis,platform chemicals,renewable resources

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